Calcium stannyl formation by organostannane dehydrogenation

Literature Information

Publication Date 2019-10-03
DOI 10.1039/C9CC07289F
Impact Factor 6.222
Authors

Louis J. Morris, Michael S. Hill, Ian Manners, Claire L. McMullin, Mary F. Mahon, Nasir A. Rajabi


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Abstract

Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.

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