Phase transitions in tantalum-modified silver niobate ceramics for high power energy storage

Literature Information

Publication Date 2018-12-10
DOI 10.1039/C8TA10075F
Impact Factor 12.732
Authors

Li Jin, Qingyuan Hu, Kun Yu, Yongyong Zhuang, Giuseppe Viola, Zhuo Xu, Xiaoyong Wei


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Abstract

Ag(Nb0.8Ta0.2)O3 is used here as a model system to shed light on the nature of the low temperature phase behavior of the unsubstituted parent compound AgNbO3, which is an important material for high-power energy storage applications. The three dielectric anomalies previously identified as M1 ↔ M2, Tf and M2 ↔ M3 transitions in AgNbO3 ceramics are found to be intimately related to the polarization the behavior of the B-site cations. In particular, the M1 ↔ M2 transition is found to involve the disappearance of original ferroelectric polar structure in the M1 phase. Analysis of weak-field and strong field hysteresis loops in the M2 region below Tf suggests the presence of a weakly-polar structure exhibiting antipolar behavior (i.e., a non-compensated antiferroelectric), which can be considered as ferrielectric (FIE). Modeling of the permittivity data using the Curie–Weiss law indicates that the Curie temperature is close to the freezing temperature, Tf, which can be regarded as the Curie point of the FIE phase. Substitution by Ta5+ in this system enhances the stability of the weakly polar/antiferroelectric state, giving rise to an increased energy storage density of 3.7 J cm−3 under an applied field of 27 MV m−1, one of the highest values ever reported for a dielectric ceramic. Furthermore, the energy storage capability remains approximately constant at around 3 J cm−3 up to 100 °C, at an applied field of 22 MV m−1.

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Source Journal

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
Self-citation Rate: 4.7%
Articles per Year: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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