![3,7-Di(1,1':3',1''-terphenyl-5'-yl)-10,11,12,13-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-ol 5-oxide structure](https://static.chemtradehub.com/structs/135/1352810-38-8-3f10.webp "3,7-Di(1,1':3',1''-terphenyl-5'-yl)-10,11,12,13-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-ol 5-oxide structure")
3,7-Di(1,1':3',1''-terphenyl-5'-yl)-10,11,12,13-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-ol 5-oxide
CAS Number:
1352810-38-8
Molecular Formula:
C53H39O4P
Base-promoted C–C bond cleavage for the synthesis of 2,3,4-trisubstituted pyrroles from N-propargyl β-enaminones
Literature Information
Publication Date
2018-09-19
DOI
10.1039/C8QO00801A
Impact Factor
5.281
Authors
Bailu Ge, Weiwei Lv, Jia Yu, Shangyun Xiao, Guolin Cheng
View Original
Abstract
A base-promoted selective cleavage of an unstrained C(CO)–C(sp2) bond of N-propargyl β-enaminones under transition metal- and oxidant-free conditions has been established. This method allows the formation of a new C(sp2)–C(sp2) bond for the synthesis of 2,3,4-trisubstituted pyrroles under mild reaction conditions with broad functional group tolerance.
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Source Journal
Organic Chemistry Frontiers
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7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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