The anionic ring-opening polymerization of N-(methanesulfonyl)azetidine
Literature Information
Publication Date
2018-02-26
DOI
10.1039/C8PY00074C
Impact Factor
5.582
Authors
Louis Reisman, Elizabeth A. Rowe, Qiaoli Liang, Paul A. Rupar
View Original
Abstract
The anionic ring-opening polymerization (AROP) of an azetidine is reported for the first time. The AROP of N-(methanesulfonyl)azetidine (MsAzet), initiated by nBuN(K)Ms, occurs in DMSO at elevated temperatures to form p(MsAzet) as a branched polymer. The polymerization is first order with respect to MsAzet and the number of active chain ends remains constant during the polymerization. Polymer branching occurs due to chain transfer through deprotonation of the methanesulfonyl group, which in turn can initiate a new polymer chain. Evidence for transfer to DMSO is also presented.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine structure](https://static.chemtradehub.com/structs/120/1206594-08-2-7afb.webp "4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine structure")
4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine
CAS Number:
1206594-08-2
Molecular Formula:
C19H28BNO3
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