Iron catalysed selective reduction of esters to alcohols

Literature Information

Publication Date 2018-12-18
DOI 10.1039/C8OB02661K
Impact Factor 3.876
Authors

Sem Raj Tamang, Anthony F. Cozzolino, Michael Findlater


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Abstract

The reaction of (dppBIAN)FeCl2 with 3 equivalents of n-BuLi affords a catalytically active anionic Fe complex; the nature of the anionic complex was probed using EPR and IR experiments and is proposed to involve a dearomatized, radical, ligand scaffold. This complex is an active catalyst for the hydrosilylation of esters to afford alcohols; loadings as low as 1 mol% were employed.

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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
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