Direct synthesis of indenes via a rhodium-catalyzed multicomponent Csp2–H annulation reaction

Literature Information

Publication Date 2018-10-15
DOI 10.1039/C8OB02359J
Impact Factor 3.876
Authors

Pierre Querard, Chao-Jun Li


View Original

Abstract

A highly efficient, direct and multicomponent route for the synthesis of indenes is reported herein. This process is catalyzed by a rhodium(III) complex and conducted under very mild conditions, making the overall process atom and step-economical. DFT mechanistic studies were performed to explore the mechanism of this reaction system.

Related Literature

Lactic acid production from glucose over polymer catalysts in aqueous alkaline solution under mild conditions

Xincheng Wang, Yanlei Song, Chongpin Huang, Fengbing Liang, Biaohua Chen

2014-06-26 Paper

DOI: 10.1039/C4GC00811A

Back cover

Cover

DOI: 10.1039/C4GC90043J

Electrodeposited CZTS solar cells from Reline electrolyte

Hao Chen, Qinyan Ye, Xulin He, Jingjing Ding, Yongzheng Zhang, Junfeng Han, Jiang Liu, Cheng Liao, Jun Mei, Woonming Lau

2014-05-13 Paper

DOI: 10.1039/C4GC00142G

Ruthenium complexes of tetradentate bipyridine ligands: highly efficient catalysts for the hydrogenation of carboxylic esters and lactones

Wei Li, Jian-Hua Xie, Ming-Lei Yuan, Qi-Lin Zhou

2014-06-13 Communication

DOI: 10.1039/C4GC00835A

Gold supported on titania for specific monohydrogenation of dinitroaromatics in the liquid phase

Shuang-Shuang Liu, Xiang Liu, Lei Yu, Yong-Mei Liu, He-Yong He, Yong Cao

2014-06-26 Paper

DOI: 10.1039/C4GC00869C

Designing ionic liquids for absorptive cooling

Kiki Adi Kurnia, João A. P. Coutinho

2014-06-17 Communication

DOI: 10.1039/C4GC00954A

Front cover

Cover

DOI: 10.1039/C4GC90035A

Furfural from corn stover hemicelluloses. A mineral acid-free approach

Hilda Gómez Bernal, Luca Bernazzani

2014-05-15 Communication

DOI: 10.1039/C4GC00450G

Transitioning organic synthesis from organic solvents to water. What's your E Factor?

Bruce H. Lipshutz, Subir Ghorai

2014-07-02 Critical Review

DOI: 10.1039/C4GC00503A

You might also like

Compound Q&A

How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?

2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...

615-45-22-Methylbenzene-1,4-...
Compound Q&A

Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?

(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...

132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A

What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?

(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...

871826-15-2(6-Chloropyridazin-3...
Compound Q&A

What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?

2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...

77772-72-62-Fluoro-3-methylphe...
Compound Q&A

What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?

When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...

177476-75-43-Methoxy-4-nitroben...
Compound Q&A

What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?

When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...

211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A

What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?

4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...

90347-86-74-Ethynylbenzamide
Compound Q&A

What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?

3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...

186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A

What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?

(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...

500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A

What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?

Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...

102196-18-92-[4-(Hydroxymethyl)...

Source Journal

Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
CiteScore: 3.4
Self-citation Rate: 10.3%
Articles per Year: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.