Formation of ozone by solid state reactions

Literature Information

Publication Date 2018-06-15
DOI 10.1039/C8CP03020K
Impact Factor 3.676
Authors

Lahouari Krim, Mindaguas Jonusas, Gianfranco Vidali


View Original

Abstract

We studied the isotopic composition of ozone formed at low (3–10 K) temperature via O + O2 solid state reactions using a partially dissociated 16O/16O2 : 18O/18O2 = 1 : 1 mixture. The ozone ice has an isotopic abundance that differs from the statistical one and from gas phase studies. Ozone formation is influenced by the competition of the production of O2 (O + O or O + O3) vs. O3 (O + O2) and by the energy released in the O + O reaction. The exothermicity of the O + O reaction helps to overcome the barrier of the O + O2 reaction. Heating the ozone ice past 50 K brings about a transformation from amorphous to crystalline ice. The formation of ozone on water ice yields a blue shift of IR bands, and the yield of formed O3 increases up to the sample temperature of 100 K. When 18O/18O2 is deposited on H216O ice, formation of 18O18O16O is detected. We propose that the exothermicity of the reaction 18O + 18O drives water dissociation (16O + H2) followed by ozone formation (16O + 18O2 → 16O18O18O).

Related Literature

Molecular dynamics study of the pore formation in single layer graphene oxide by a thermal reduction process

Federico Raffone, Filippo Savazzi, Giancarlo Cicero

2021-04-26 Paper

DOI: 10.1039/D1CP00134E

The many-body expansion for aqueous systems revisited: III. Hofmeister ion–water interactions

Kristina M. Herman, Joseph P. Heindel

2021-04-06 Paper

DOI: 10.1039/D1CP00409C

An ultra-sensitive gas sensor based on a two-dimensional manganese porphyrin monolayer

Ze-Wen Hao, Mi-Mi Dong, Rui-Qin Zhang, Chuan-Kui Wang, Xiao-Xiao Fu

2021-04-22 Paper

DOI: 10.1039/D1CP00747E

Apparent autocatalysis due to liquefaction: thermal decomposition of ammonium 3,4,5-trinitropyrazolate

Nikita V. Muravyev, Konstantin A. Monogarov, Igor L. Dalinger, Nobuyoshi Koga, Alla N. Pivkina

2021-04-22 Paper

DOI: 10.1039/D1CP01530C

Encapsulating aluminum nanoparticles into carbon nanotubes for combustion: a molecular dynamics study

Liang Song, Feng-Qi Zhao, Si-Yu Xu, Xue-Hai Ju

2021-04-22 Paper

DOI: 10.1039/D1CP01135A

Site-selective soft X-ray absorption as a tool to study protonation and electronic structure of gas-phase DNA

Xin Wang, Sivasudhan Rathnachalam, Klaas Bijlsma, Wen Li, Ronnie Hoekstra, Markus Kubin, Martin Timm, Bernd von Issendorff, Vicente Zamudio-Bayer, Shirin Faraji, Thomas Schlathölter

2021-05-10 Paper

DOI: 10.1039/D1CP01014J

Copper (Cu2+) ion-induced misfolding of tau protein R3 peptide revealed by enhanced molecular dynamics simulation

Gao Tu, Xianquan Ming, Haiqing Zhan, Feng Zhan

2021-04-26 Paper

DOI: 10.1039/D0CP05744D

La induced Si3 trimer bilayer on the Si(111) surface

Jing Xu

2021-04-20 Paper

DOI: 10.1039/D1CP01351C

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.