Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks
Literature Information
Publication Date
2017-09-29
DOI
10.1039/C7PY01607G
Impact Factor
5.582
Authors
Jongkook Hwang, Hui-Chun Lee, Markus Antonietti, Bernhard V. K. J. Schmidt
View Original
Abstract
Free radical and RAFT polymerization of vinyl esters with different molecular dimensions are conducted in the nanochannels of metal–organic-frameworks (MOFs). The combination of MOFs with the RAFT technique enables the synthesis of highly isotactic poly(vinyl ester)s with a controlled molecular weight and narrow molecular weight distribution, and stereocontrolled isotactic-block-atactic vinyl ester block copolymers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
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