![2-(Methylsulfonyl)-2,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole structure](https://static.chemtradehub.com/structs/122/1226781-80-1-09d5.webp "2-(Methylsulfonyl)-2,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole structure")
2-(Methylsulfonyl)-2,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole
CAS Number:
1226781-80-1
Molecular Formula:
C6H9N3O2S
Probing the first steps of photoinduced free radical polymerization at water–oil interfaces
Literature Information
Publication Date
2017-10-31
DOI
10.1039/C7PY01414G
Impact Factor
5.582
Authors
Denisa Darvasiová, Zuzana Barberiková, Anna Eibel, Max Schmallegger, Georg Gescheidt, Michal Zalibera, Dmytro Neshchadin
View Original
Abstract
Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine
CAS Number:
1206594-08-2
Molecular Formula:
C19H28BNO3
![2-Methyl-2-propanyl 1,6-diazaspiro[3.4]octane-6-carboxylate structure](https://static.chemtradehub.com/structs/115/1158749-79-1-81ee.webp "2-Methyl-2-propanyl 1,6-diazaspiro[3.4]octane-6-carboxylate structure")
2-Methyl-2-propanyl 1,6-diazaspiro[3.4]octane-6-carboxylate
CAS Number:
1158749-79-1
Molecular Formula:
C11H20N2O2
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