Chalcogenide hybrid inorganic/organic polymers (CHIPs) via inverse vulcanization and dynamic covalent polymerizations
Literature Information
Publication Date
2017-04-19
DOI
10.1039/C7PY00587C
Impact Factor
5.582
Authors
Yueyan Zhang, Katrina M. Konopka, Richard S. Glass, Kookheon Char
View Original
Abstract
We report on the preparation and modification of chalcogenide hybrid inorganic/organic polymer (CHIPs) via the inverse vulcanization of elemental sulfur with styrenics to afford low glass transition (Tg) copolymers. Furthermore, poly(sulfur-random-styrene) (poly(S-r-Sty)) can be further utilized as reactive liquid resins that are miscible with a wider range of styrenic, acrylate and allylic comonomers. We describe a new process termed, dynamic covalent polymerization (DCP), where the dynamic S–S bonds in poly(S-r-Sty) liquid polysulfides were thermally activated to generate sulfur radicals that added to vinylic comonomers to prepare novel terpolymer CHIPs. Using this sequential process we demonstrate the ability to incorporate functional comonomers that were otherwise immiscible with liquid sulfur.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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