Intricate kinetics: in situ FTIR-spectroscopy discloses a phase change during ionic liquid synthesis
Literature Information
A. Ohligschläger, M. A. Liauw
The kinetics of the methylation of triethylamine (NEt3) with dimethyl carbonate (DMC) in methanol have been investigated by means of in situ ATR-IR-spectroscopy. The data show an autocatalytic influence of the ionic product on reaction kinetics. A bend in the reaction rate progress indicates a sudden change from solvated ions to a microstructured biphasic system, which is reflected in the dependence of the reaction rate constant on the product concentration and the Hildebrand parameter.
Recommended Journals

Russian Journal of Applied Chemistry

Russian Journal of Coordination Chemistry

Current Opinion in Solid State & Materials Science

Acta Materialia

Russian Chemical Bulletin

Organic Process Research & Development

Russian Journal of Organic Chemistry

Saudi Pharmaceutical Journal

Russian Journal of Bioorganic Chemistry

Russian Journal of General Chemistry
Related Literature
Insight into the structures of unusual base pairs in RNA complexes containing a primer/template/adenosine ligand
Yuliya Dantsu, Ying Zhang, Wen Zhang
DOI: 10.1039/D3CB00137G
Room temperature phosphorescence optosensing of benzo[a]pyrene in water using halogenated molecularly imprinted polymers
José M. Traviesa-Alvarez, Israel Sánchez-Barragán, José M. Costa-Fernández, Rosario Pereiro, Alfredo Sanz-Medel
DOI: 10.1039/B616919H
Development of lacto-series ganglioside fluorescent probe using late-stage sialylation and behavior analysis with single-molecule imaging
Naoko Komura, Yukako Yoshida, Eriko Yamaguchi, Ami Hasegawa
DOI: 10.1039/D2CB00083K
Dual-action gallium-flavonoid compounds for combating Pseudomonas aeruginosa infection
Bingjie Han, Yu Guo, Richard Y T Kao, Hongyan Li, Hongzhe Sun, Wei Xia
DOI: 10.1039/D3CB00033H
Mutant polymerases capable of 2′ fluoro-modified nucleic acid synthesis and amplification with improved accuracy
Trevor A. Christensen, Kristi Y. Lee, Simone Z. P. Gottlieb, Mikayla B. Carrier, Aaron M. Leconte
DOI: 10.1039/D2CB00064D
Molecular dynamics modelling of the interaction of a synthetic zinc-finger miniprotein with DNA
Soraya Learte-Aymamí, José L. Mascareñas
DOI: 10.1039/D3CB00053B
The development of novel organically modified sol-gel media for use with ATR/FTIR sensing
K. Flavin, J. Mullowney, B. Murphy, E. Owens, P. Kirwan, K. Murphy, H. Hughes, P. McLoughlin
DOI: 10.1039/B612402J
Potential shift correction in multivariate curve resolution of voltammetric data. General formulation and application to some experimental systems
Arístides Alberich, José Manuel Díaz-Cruz, Cristina Ariño, Miquel Esteban
DOI: 10.1039/B715667G
You might also like
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.



![[2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-3-yl]dicyclohexylphosphane structure [2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-3-yl]dicyclohexylphosphane structure](https://static.chemtradehub.com/structs/787/787618-22-8-dda2.webp)
