Chiral supramolecular organization from a sheet-like achiral gel: a study of chiral photoinduction

Literature Information

Publication Date 2017-05-05
DOI 10.1039/C7CP01739A
Impact Factor 3.676
Authors

Jorge Royes, Víctor Polo, Santiago Uriel, Luis Oriol, Milagros Piñol, Rosa M. Tejedor


View Original

Abstract

Chiral photoinduction in a photoresponsive gel based on an achiral 2D architecture with high geometric anisotropy and low roughness has been investigated. Circularly polarized light (CPL) was used as a chiral source and an azobenzene chromophore was employed as a chiral trigger. The chiral photoinduction was studied by evaluating the preferential excitation of enantiomeric conformers of the azobenzene units. Crystallographic data and density functional theory (DFT) calculations show how chirality is transferred to the achiral azomaterials as a result of the combination of chiral photochemistry and supramolecular interactions. This procedure could be applied to predict and estimate chirality transfer from a chiral physical source to a supramolecular organization using different light-responsive units.

Related Literature

Selective catalytic oxidation using supported gold–platinum and palladium–platinum nanoalloys prepared by sol-immobilisation

Virginie Peneau, Qian He, Gregory Shaw, Simon A. Kondrat, Thomas E. Davies, Peter Miedziak, Michael Forde, Nikolaos Dimitratos, Christopher J. Kiely, Graham J. Hutchings

2013-04-02 Paper

DOI: 10.1039/C3CP50361E

The exciton dynamics in tetracene thin films

Murad J. Y. Tayebjee, Raphaël G. C. R. Clady, Timothy W. Schmidt

2013-07-19 Paper

DOI: 10.1039/C3CP52609G

Resonance optical manipulation of nano-objects based on nonlinear optical response

Tetsuhiro Kudo, Hajime Ishihara

2013-07-08 Perspective

DOI: 10.1039/C3CP51969D

Tuning the dissolution kinetics of wollastonite via chelating agents for CO2 sequestration with integrated synthesis of precipitated calcium carbonates

Huangjing Zhao, Youngjune Park, Dong Hyun Lee, Ah-Hyung Alissa Park

2013-07-04 Paper

DOI: 10.1039/C3CP52459K

Shape-dependent two-photon absorption in two-dimensionally extended benzoporphyrin arrays

Pyosang Kim, Sujin Ham, Juwon Oh, Hiroki Uoyama, Hajime Watanabe, Kazunari Tagawa, Hidemitsu Uno, Dongho Kim

2013-04-04 Communication

DOI: 10.1039/C3CP50166C

Li diffusion through doped and defected graphene

Deya Das, Seungchul Kim, Kwang-Ryeol Lee, Abhishek K. Singh

2013-07-17 Paper

DOI: 10.1039/C3CP52891J

Observing reduction of 4-nitrobenzenthiol on gold nanoparticlesin situ using surface-enhanced Raman spectroscopy

Xiaoqian Ren, Tingting You, Li Jiang, Hongyan Zhang, Penggang Yin, Lin Guo

2013-06-18 Paper

DOI: 10.1039/C3CP51385H

Conformational preferences of furan- and thiophene-based arylamides: a combined computational and experimental study

Jhenny F. Galan, Chi Ngong Tang, Shubhashis Chakrabarty, Zhiwei Liu, Vojislava Pophristic

2013-05-08 Paper

DOI: 10.1039/C3CP50353D

Iron cation catalyzed reduction of N2O by CO: gas-phase temperature dependent kinetics

Joshua J. Melko, Shaun G. Ard, Joseph A. Fournier, Jun Li, Nicholas S. Shuman, Hua Guo, Albert A. Viggiano

2013-05-31 Paper

DOI: 10.1039/C3CP50335F

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.