Derivatization and interlaminar debonding of graphite–iron nanoparticle hybrid interfaces using Fenton chemistry
Literature Information
Neha Agarwal, Ruma Bhattacharyya, Narendra K. Tripathi, Sanjay Kanojia, Debmalya Roy, Kingsuk Mukhopadhyay, Namburi Eswara Prasad
The interfacial debonding of graphite lattices using iron (Fe) nanoparticles and Fenton's reagent is reported, towards the scalable production of few-layer graphene flakes. Acoustic cavitation via a sonochemical route was adapted to produce iron and iron oxide nanoparticles in the graphite matrix. The oxygenated species were introduced into the graphite lattice using a physical method, and then Fenton chemistry was utilized to generate localized hydroxyl radicals at the Fe nanoparticle–graphite interfaces for zipping and self-exfoliation of the defected graphite lattices. The functional groups were found to have been introduced predominately at the periphery of the flake, confirming that the lateral dimension of graphene had not been affected, and at the same time, good dispersion in organic solvents had been achieved. Defect engineering could be modulated at the organic–inorganic hybrid interfaces, in order to control the zipping rate and regulate the degree of functionalization and the lateral dimensions of the graphene sheet.
Related Literature
A mathematical model of a slurry reactor for the direct synthesis of hydrogen peroxide
Fabio Pizzetti, Vittoria M. A. Granata, Umberto Riva, Filippo Rossi, Maurizio Masi
DOI: 10.1039/C9RE00309F
Catalyst Acquisition by Data Science (CADS): a web-based catalyst informatics platform for discovering catalysts
Yuzuru Tanaka
DOI: 10.1039/D0RE00098A
Continuous flow synthesis of the URAT1 inhibitor lesinurad
Mariana C. F. C. B. Damião, Henrique M. Marçon, Julio Cezar Pastre
DOI: 10.1039/C9RE00483A
Pyrolysis of mixtures of methane and ethane: activation of methane with the aid of radicals generated from ethane
Hitoshi Ogihara, Hiroki Tajima, Hideki Kurokawa
DOI: 10.1039/C9RE00400A
Refinery integration of lignocellulose for automotive fuel production via the bioCRACK process and two-step co-hydrotreating of liquid phase pyrolysis oil and heavy gas oil
Anna Huber, Samir Reiter, Mario Lukasch, Berndt Hammerschlag, Julia Außerleitner, Daniela Painer, Peter Pucher, Matthäus Siebenhofer, Nikolaus Schwaiger
DOI: 10.1039/C9RE00352E
Constructing well-defined star graft copolymers
Yan Deng, Sen Zhang, Guolin Lu, Xiaoyu Huang
DOI: 10.1039/C2PY20622F
Chiral polymeric microspheres grafted with optically active helical polymer chains: a new class of materials for chiral recognition and chirally controlled release
Ci Song, Chaohong Zhang, Fangjie Wang, Wantai Yang, Jianping Deng
DOI: 10.1039/C2PY20546G
pH and reduction dual-responsive nanogel cross-linked by quaternization reaction for enhanced cellular internalization and intracellular drug delivery
Zhaohui Tang, Hai Sun, Xuesi Chen
DOI: 10.1039/C2PY20871G
NH3-SCR of NO with novel active, supported vanadium-containing Keggin-type heteropolyacid catalysts
Anna Bukowski, Leonhard Schill, David Nielsen, Susanne Mossin, Anders Riisager, Jakob Albert
DOI: 10.1039/D0RE00033G
Redox initiation of bulk thiol–ene polymerizations
Megan A. Cole, Katherine C. Jankousky
DOI: 10.1039/C2PY20843A
You might also like
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure 1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure](https://static.chemtradehub.com/structs/192/19210-12-9-ecae.webp)
