Gold-catalyzed bis(stannylation) of propiolates

Literature Information

Publication Date 2016-05-10
DOI 10.1039/C6QO00128A
Impact Factor 5.281
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Abstract

The first example of gold-catalyzed addition of Sn–Sn bonds to alkynes is reported. A cationic gold(I) complex bearing a phosphite ligand is reported to efficiently catalyze the bis(stannylation) of propiolates with hexabutylditin under mild conditions.

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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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