Transformable nanostructures of cholesteryl-containing rhomboidal metallacycles through hierarchical self-assembly
Literature Information
Li-Jun Chen, Bo Jiang, Hai-Bo Yang
The precise morphological control of supramolecular structures is of pivotal importance in the fields of nanoscience and nanotechnology. We describe herein a successful example of transformable nanostructures from cholesteryl-containing rhomboidal metallacycles. Various interesting nanostructures such as flowers and tadpole shaped structures were successfully obtained through the hierarchical self-assembly of two well-defined rhomboidal metallacycles prepared by coordination-driven self-assembly. Variation of the linker structure and solvent composition was found to trigger such drastic morphological changes of aggregates as revealed by microscopy studies.
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Organic Chemistry Frontiers

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry



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