Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions‡
Literature Information
Publication Date
2016-02-15
DOI
10.1039/C6QO00014B
Impact Factor
5.281
Authors
Christophe Lévêque, Ludwig Chenneberg, Vincent Corcé, Jean-Philippe Goddard, Cyril Ollivier, Louis Fensterbank
View Original
Abstract
Primary alkyl bis-catecholato silicates have been successfully engaged with aryl and heteroaryl bromide substrates in photoredox/nickel dual catalysis to provide aryl- and heteroaryl-alkyl cross coupling products. The scope of the transformation is wide and the process appears to be tolerant of various functional groups present. Of note, most examples rely on the challenging use of highly reactive primary radicals which constitutes a significant advance in these cross coupling reactions.
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Source Journal
Organic Chemistry Frontiers
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