![Ethyl 4-[8-chloro(5,5,6,6,7-~2~H_5_)-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene]-1-piperidinecarboxylate structure](https://static.chemtradehub.com/structs/102/1020719-57-6-37e2.webp "Ethyl 4-[8-chloro(5,5,6,6,7-~2~H_5_)-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene]-1-piperidinecarboxylate structure")
Ethyl 4-[8-chloro(5,5,6,6,7-~2~H_5_)-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidene]-1-piperidinecarboxylate
CAS Number:
1020719-57-6
Molecular Formula:
C22H18D5ClN2O2
Polymerization of α-(halomethyl)acrylates through sequential nucleophilic attack of dithiols using a combination of addition–elimination and click reactions
Literature Information
Publication Date
2016-12-27
DOI
10.1039/C6PY02145J
Impact Factor
5.582
Authors
Yasuhiro Kohsaka, Keito Hagiwara, Keiichiro Ito
View Original
Abstract
Polymerization of α-(halomethyl)acrylates and dithiols was achieved by the combination of SN2′ (addition–elimination) and subsequent thiol–ene click reactions. A Bu3P catalyst and an excess amount of a base that does not yield an acidic salt, e.g., 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) or K2CO3, were key for achieving Mn > 104.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure](https://static.chemtradehub.com/structs/159/1595319-98-4-33e7.webp "(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure")
(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide
CAS Number:
1595319-98-4
Molecular Formula:
C24H28NOPS
Ethyl 2,4-bis(trifluoromethyl)-5-pyrimidinecarboxylate
CAS Number:
188781-15-9
Molecular Formula:
C9H6F6N2O2
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