Aqueous RAFT at pH zero: enabling controlled polymerization of unprotected acyl hydrazide methacrylamides
Literature Information
Publication Date
2016-10-17
DOI
10.1039/C6PY01563H
Impact Factor
5.582
Authors
Emily A. Hoff, Brooks A. Abel, Chase A. Tretbar, Charles L. McCormick, Derek L. Patton
View Original
Abstract
We report aqueous RAFT polymerization at pH = 0 mediated by a novel imidazolium-containing chain transfer agent. In 1 M HCl, unprecedented controlled polymerization and chain-extension of unprotected acyl hydrazide methacrylamides is achieved enabling the synthesis of well-defined acyl hydrazide functionalized polymer scaffolds of interest for dynamic covalent and bioconjugation strategies.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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