Ligand effects on cooperative supramolecular polymerization of platinum(ii) acetylide complexes

Literature Information

Publication Date 2016-08-31
DOI 10.1039/C6PY01440B
Impact Factor 5.582
Authors

Zhao Gao, Junlong Zhu, Yifei Han, Xiaoqin Lv, Xiaolong Zhang, Feng Wang


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Abstract

A rod-like platinum(II) acetylide monomer with a less bulky ligand is prone to form helical nanofibers and organogels via a cooperative nucleation–elongation mechanism, whilst no aggregation can be detected for the bulky counterpart, thus demonstrating the significant role of ligand effects on the macroscopic supramolecular polymerization behaviors.

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