Hybrid organic–inorganic supramolecular hydrogel reinforced with CePO4 nanowires
Literature Information
Publication Date
2016-09-30
DOI
10.1039/C6PY01127F
Impact Factor
5.582
Authors
Chenyan Liu, Guolei Xiang, Yuchao Wu, Steven J. Barrow, Matthew J. Rowland, David E. Clarke, Guanglu Wu, Oren A. Scherman
View Original
Abstract
We report a method to enhance the stiffness in the rheological yield strain of cucurbit[8]uril (CB[8])-based hydrogels by introducing inorganic nanowires (NWs) into the supramolecular networks. The supramolecular hydrogel is comprised of methylviologen-functionalised poly(vinyl alcohol) (PVA-MV), hydroxyethyl cellulose with naphthyl moieties (HEC-Np) and CB[8] macrocyclic hosts. The gel structure can be effectively enhanced by the framework supporting effects of cerous phosphate NWs and additional hydrogen bonding interactions between the NWs and the PVA-MV/HEC-Np polymers. The high aspect ratio NWs serve as a “skeleton” for the network providing extra physical crosslinks, resulting in a single continuous phase hybrid supramolecular network with improved strength, presenting a general approach to reinforce soft materials.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
4-(Bromomethyl)-1-cyclohexyl-2-(trifluoromethyl)benzene
CAS Number:
800381-60-6
Molecular Formula:
C14H16BrF3
5-(2-Methyl-3-furyl)-4-phenyl-2,4-dihydro-3H-1,2,4-triazole-3-thione
CAS Number:
346464-59-3
Molecular Formula:
C13H11N3OS
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