Partial molar volumes of linear hydrocarbons in methanol in the very dilute region. Intermolecular interactions. H-bond effects
Literature Information
Ester F. G. Barbosa, Susana M. C. Sousa, M. Soledade C. S. Santos, Isabel M. S. Lampreia
Limiting partial molar volumes VB∞ for the linear hydrocarbons, C5, C6 , C7, C8 and C10 in methanol were determined with a vibrating tube densimeter at 24.994°C (ITS-90). VB∞ and bV were discussed in terms of solute–solvent and solute–solute molecular interactions, focusing on H-bond cleavage, hydrocarbon short-range correlations of molecular orbitals and conformational effects. VB∞ (HS)/VB (HS) values calculated according to Lee's hard-sphere mixtures model are compared with experimental values. A discussion is presented and deviations are interpreted in terms of size, shape, packing densities and H-bond effects.
Related Literature
Global exploration of the energy landscape of solids on the ab initio level
K. Doll, J. C. Schön, M. Jansen
DOI: 10.1039/B709943F
Probing the evaporation of ternary ethanol–methanol–water droplets by cavity enhanced Raman scattering
Chris R. Howle, Chris J. Homer, Rebecca J. Hopkins, Jonathan P. Reid
DOI: 10.1039/B706211G
Porphyrin linked poly(pyridyl)-based conjugates as artificial photosynthetic reaction centre models
DOI: 10.1039/B708166A
Protein resistance of (ethylene oxide)n monolayers at the air/water interface: effects of packing density and chain length
Yijian Chen, Guangzhao Zhang, Shihe Yang
DOI: 10.1039/B711037E
Multiphoton dissociation dynamics of BrCl and the BrCl+cation
Olivier P. J. Vieuxmaire, N. Hendrik Nahler, Richard N. Dixon, Michael N. R. Ashfold
DOI: 10.1039/B709222A
The effect of parity violation on kinetic models of enantioselective autocatalysis
Gábor Lente
DOI: 10.1039/B711546F
Synthesis, characterization, and intracellular uptake of carboxyl-terminated poly(amidoamine) dendrimer-stabilized iron oxide nanoparticles
Xiangyang Shi, Thommey P. Thomas, Lukasz A. Myc, Alina Kotlyar, James R. Baker, Jr
DOI: 10.1039/B709147H
On the photochemistry of IONO2 : absorption cross section (240–370 nm) and photolysis product yields at 248 nm
D. M. Joseph, S. H. Ashworth, J. M. C. Plane
DOI: 10.1039/B709465E
You might also like
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












![2-Bromodibenzo[b,d]furan structure 2-Bromodibenzo[b,d]furan structure](https://static.chemtradehub.com/structs/86-/86-76-0-1814.webp)

