![2-[2-(2-Methoxyethoxy)ethoxy]-2-methylpropane structure](https://static.chemtradehub.com/structs/527/52788-79-1-71c1.webp "2-[2-(2-Methoxyethoxy)ethoxy]-2-methylpropane structure")
All-thiophene-based conjugated porous organic polymers
Literature Information
Publication Date
2016-07-15
DOI
10.1039/C6PY00725B
Impact Factor
5.582
Authors
Peng-Fei Wang, Hua Wang, Bao-Hang Han
View Original
Abstract
Novel all-thiophene-based conjugated porous organic polymers (ThPOP-1 and ThPOP-2) were synthesized through ferric chloride-catalyzed oxidative coupling polymerization at room temperature. ThPOP-1 and ThPOP-2 were characterized via solid-state 13C CP/MAS NMR spectroscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis. The sulfur content of the obtained polymers is approximately 36 wt%. The Brunauer–Emmett–Teller specific surface area results of ThPOP-1 and ThPOP-2 are 1050 and 160 m2 g−1, respectively. Carbon dioxide adsorption isotherms show that ThPOP-1 (15.0 wt%) exhibits a larger uptake capacity than ThPOP-2 (4.0 wt%) at 273 K and 1.0 bar. Hydrogen uptake is also excellent for ThPOP-1 (2.23 wt%) at 77 K and 1.0 bar.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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CAS Number:
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