Scanning probe microscopy for real-space observations of local chemical reactions induced by a localized surface plasmon

Literature Information

Publication Date 2019-07-08
DOI 10.1039/C9CP02100K
Impact Factor 3.676
Authors

Emiko Kazuma, Yousoo Kim


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Abstract

Localised surface plasmon (LSP) resonance has attracted considerable attention in recent years as an efficient driving force for chemical reactions. The chemical reactions induced by LSP are classified into two types, namely, redox reactions based on plasmon-induced charge separation (PICS) and chemical reactions induced by the direct interaction between LSP and molecules (plasmon-induced chemical reactions). Although both types of reactions have been extensively studied, the mechanisms of PICS and plasmon-induced chemical reactions remain unexplained and controversial because conventional macroscopic methods can hardly grasp the local chemical reactions induced by LSP. In order to obtain mechanistic insights, nanoscale observations and investigations are necessary. Scanning probe microscopy (SPM) is a powerful experimental tool to investigate not only the surface morphology but also the physical and chemical properties of samples at a high spatial resolution. In this perspective review, we first explain SPM combined with optical excitation, and then, review the recent studies using SPM techniques for real-space observations of the chemical reactions induced by LSP.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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