Hydrated forms of fluoroacetic acid: a rotational study

Literature Information

Publication Date 2016-07-30
DOI 10.1039/C6CP04735A
Impact Factor 3.676
Authors

Luca Evangelisti, Lorenzo Spada, Susana Blanco, Walther Caminati


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Abstract

The rotational spectra of two conformers of the 1 : 1 adduct of fluoroacetic acid with water have been assigned by pulsed jet Fourier transform microwave spectroscopy. Their shapes differ according to the trans and cis forms of the fluoroacetic acid moiety. This is in contrast to the rotational spectrum of the monomer, for which the cis form has not been observed. Details of the hydrogen bond, structure, dynamics and energetic features of the two species are given.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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