Metallic cyanoacetylides of copper, silver and gold: generation and structural characterization

Literature Information

Publication Date 2016-09-20
DOI 10.1039/C6CP04474C
Impact Factor 3.676
Authors

Carlos Cabezas, Carmen Barrientos, Antonio Largo, Jean-Claude Guillemin, J. L. Alonso


View Original

Abstract

The metallic cyanoacetylides CuCCCN, AgCCCN, and AuCCCN have been synthesized in the throat of a pulsed supersonic expansion by reaction of metal vapors, produced by laser ablation, and BrCCCN. Their pure rotational spectra in the (X1Σ+) electronic ground state were observed by Fourier transform microwave spectroscopy in the 2–10 GHz frequency region. Importantly, the rotational spectroscopy constants determined from the analysis of the rotational spectra clearly established the existence of metal–CCCN arrangements for all the mentioned cyanoacetylides. A study of the chemical bonding by means of a topological analysis of the electron density helps to understand the preference for metal–C bonding over metal–N bonding.

Related Literature

Simple and efficient synthesis of cyclic carbonates using quaternized glycine as a green catalyst

Jose Tharun, George Mathai, Roshith Roshan, Amal Cherian Kathalikkattil, Kim Bomi, Dae-Won Park

2013-04-23 Communication

DOI: 10.1039/C3CP51158H

Stability and electronic properties of ultrathin films of silicon and germanium

Dimitrios Kaltsas, Leonidas Tsetseris

2013-04-15 Paper

DOI: 10.1039/C3CP50944C

Switching and charging of a ruthenium dye on Ag(111)

Nadine Hauptmann, Christian Hamann, Richard Berndt

2013-05-10 Communication

DOI: 10.1039/C3CP51023A

Visible light-induced OH radicals in Ga2O3: an EPR study

Zeev Tzitrinovich, Anat Lipovsky, Aharon Gedanken, Rachel Lubart

2013-06-11 Paper

DOI: 10.1039/C3CP00102D

Computational study of peptide bond formation in the gas phase through ion–molecule reactions

Pilar Redondo, Henar Martínez, Álvaro Cimas, Carmen Barrientos, Antonio Largo

2013-06-07 Paper

DOI: 10.1039/C3CP51535D

Separation of cobalt and nickel by solvent extraction with two mutually immiscible ionic liquids

Sil Wellens, Ben Thijs, Claudia Möller, Koen Binnemans

2013-04-12 Paper

DOI: 10.1039/C3CP50819F

Infiltrating sulfur in hierarchical architecture MWCNT@meso C core–shell nanocomposites for lithium–sulfur batteries

Yingchao Yu, Weidong Zhou, Hao Chen, Francis J. DiSalvo, Héctor D. Abruña

2013-04-12 Communication

DOI: 10.1039/C3CP51551F

Dependence on the structure and surface polarity of ZnS photocatalytic activities of water splitting: first-principles calculations

Hai Xiao, Xiaohong Wen, William A. Goddard III, Song Li, Gaowu Qin

2013-04-22 Paper

DOI: 10.1039/C3CP50330E

You might also like

Compound Q&A

How is Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) typically synthesized?

Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) can be synth...

59713-58-5Ethyl 4-chlorothieno...
Compound Q&A

What regulatory guidelines apply to 5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2)?

5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2) is subject to various regula...

52562-50-25-Methyl-1H-indole-3...
Compound Q&A

What are the physical and chemical properties of (1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid (CAS: 223418-73-3)?

(1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid is a white...

223418-73-3(1,3-Dimethyl-2,4-di...
Compound Q&A

How should waste containing Sulfocostunolide A (CAS: 1016983-51-9) be handled?

Waste containing Sulfocostunolide A (CAS: 1016983-51-9) should be handled with c...

1016983-51-9Sulfocostunolide A
Compound Q&A

What precautions should be taken when handling Murraxocin (CAS: 88478-44-8)?

When handling Murraxocin (CAS: 88478-44-8), ensure proper personal protective eq...

88478-44-8Murraxocin
Compound Q&A

What are the physical and chemical properties of Formvar (CAS: 63148-64-1)?

Formvar (CAS: 63148-64-1) is an alkyd resin characterized by a high molecular we...

63148-64-1Formvar(R)
Compound Q&A

Is (S)-4-benzyl-2-((benzyloxy)methyl)morpholine (CAS: 205242-66-6) safe?

(S)-4-benzyl-2-((benzyloxy)methyl)morpholine is generally safe when handled with...

205242-66-6(S)-4-benzyl-2-((ben...
Compound Q&A

What industries use Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3)?

Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3) is p...

1447607-69-3Methyl 1-(5-bromo-2-...
Compound Q&A

Is 2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) safe?

2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) is generally con...

24290-47-92-Methyl-1-phenyl-1-...
Compound Q&A

How is 3-(4-Bromophenyl)-2-methylpropanoic acid (CAS: 66735-01-1) typically synthesized?

3-(4-Bromophenyl)-2-methylpropanoic acid is synthesized through a multi-step pro...

66735-01-13-(4-Bromophenyl)-2-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.