Photoinduced water splitting in pyridine water clusters

Literature Information

Publication Date 2016-08-19
DOI 10.1039/C6CP04398D
Impact Factor 3.676
Authors

Natalia Esteves-López, Stephane Coussan, Claude Dedonder-Lardeux, Christophe Jouvet


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Abstract

Ab initio calculations predict that pyridine (Py) can act as a photo-catalyst to split water by the absorption of a UV photon following the reaction Py–H2O + hν → PyH˙ + OH˙. To test this prediction, we performed two types of experiments: in the first, we characterize the electronic spectroscopy of the PyH˙ radical in the gas phase. In the second, we evidence the reaction through the UV excitation of molecular Py–(H2O)n clusters obtained in a supersonic expansion and monitoring the PyH˙ reaction product. The results show unambiguously that PyH˙ is produced, and thus that water is split using pyridine as a photo-catalyst.

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Inside front cover

Front/Back Matter

DOI: 10.1039/B919125A

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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