Observation of stable HO4+ and DO4+ ions from ion–molecule reactions in helium nanodroplets

Literature Information

Publication Date 2016-04-25
DOI 10.1039/C6CP01895E
Impact Factor 3.676
Authors

Michael Renzler, Stefan Ralser, Lorenz Kranabetter, Erik Barwa, Paul Scheier, Andrew M. Ellis


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Abstract

Ion–molecule reactions between clusters of H2/D2 and O2 in liquid helium nanodroplets were initiated by electron-induced ionization (at 70 eV). Reaction products were detected by mass spectrometry and can be explained by a primary reaction channel involving proton transfer from H3+ or H3+(H2)n clusters and their deuterated equivalents. Very little HO2+ is seen from the reaction of H3+ with O2, which is attributed to an efficient secondary reaction between HO2+ and H2. On the other hand HO4+ is the most abundant product from the reaction of H3+ with oxygen dimer, (O2)2. The experimental data suggest that HO4+ is a particularly stable ion and this is consistent with recent theoretical studies of this ion.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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