The first UV absorption band of l-tryptophan is not due to two simultaneous orthogonal electronic transitions differing in the dipole moment
Literature Information
Based on UV/Vis spectroscopic evidence obtained in this work, the first band in the absorption spectrum of L-tryptophan is largely due to a single electronic transition from the ground state to the 1Lb excited state. However, emission spectra of this compound recorded at a variable temperature in ethanol, n-butanol and diethyl ether are structureless and considerably red-shifted at room temperature; also, lowering the temperature causes the emission to become structured and to undergo such a strong blue shift that it appears to be due to the 1Lb state of the compound. Based on these findings, the formation (from the excited 1Lb state) of the excited state responsible for the structureless, markedly red-shifted emission in L-tryptophan is strongly dependent not only on the viscosity of the medium, but also on its dipolarity.
Related Literature
Palladium-catalyzed cyanation of aryl halides with in situ generated CN− from ClCF2H and NaNH2
Changjiang Yu, Xingxing Ma, Qiuling Song
DOI: 10.1039/D0QO00775G
Cavity-based applications of metallo-supramolecular coordination cages (MSCCs)
Sarita Yadav, Palanisamy Kannan, Guanyinsheng Qiu
DOI: 10.1039/D0QO00681E
Kinetic resolution of 2H-azirines via Cu(i)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides
Hua Deng, Tian-Tian Liu, Zheng-Dong Ding, Wu-Lin Yang, Xiaoyan Luo
DOI: 10.1039/D0QO00789G
An improved synthesis of the [5.6.7]-tricyclic core of cyrneine B and glaucopine C
Guo-Jie Wu, Xiu Han
DOI: 10.1039/D0QO00758G
BODIPY-amino acid conjugates – tuning the optical response with a meso-heteroatom
Marco Farinone, Joanna Cybińska, Miłosz Pawlicki
DOI: 10.1039/D0QO00481B
Nucleophile-assisted cyclization of β-propargylamino acrylic compounds catalyzed by gold(i): a rapid construction of multisubstituted tetrahydropyridines and their fused derivatives
Petr Matouš, Michal Kadaník, Marek Timoracký, Jiří Kuneš, Jana Maříková, Aleš Růžička, Milan Pour
DOI: 10.1039/D0QO00653J
Pictet–Spengler reaction based on in situ generated α-amino iminium ions through the Heyns rearrangement
Guo-bin Yang, Yong-po Zhang, Dong-dong Guo, Jin-zhong Zhao, Guang-xun Li, Zhuo Tang
DOI: 10.1039/D0QO00722F
Organic micro/nanoscale materials for photonic barcodes
Yue Hou, Zhenhua Gao, Yong Sheng Zhao, Yongli Yan
DOI: 10.1039/D0QO00613K
Modular synthesis and immunological evaluation of suspected allergenic galactooligosaccharides
Hidde Elferink, Emiel Rossing, Linqiu Cao, Dianne J. Delsing, Andre Groeneveld, Thomas J. Boltje
DOI: 10.1039/C9OB00108E
You might also like
Is 2-(2-chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) safe?
2-(2-Chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) is generally consi...
Is 2-(Benzyloxy)-5-bromobenzoic acid (CAS: 62176-31-2) safe?
2-(Benzyloxy)-5-bromobenzoic acid can be handled safely if appropriate precautio...
What is (4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride (CAS: 1159825-48-5)?
(4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride is a chemical compound ...
What is 2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54-7)?
2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54...
Are there alternatives to 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS: 102771-26-6) in synthesis?
While 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS:...
What is the market or research trend for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine-6-carboxylate (CAS: 851376-80-2)?
The market for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine...
How should waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) be handled?
Waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) should ...
How is (6-Fluoro-3-pyridinyl)boronic acid (CAS: 351019-18-6) typically synthesized?
(6-Fluoro-3-pyridinyl)boronic acid can be synthesized through the reaction of 6-...
What industries use Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9)?
Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9) finds applications in vario...
What is the market or research trend for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4)?
The market for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4) is g...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![Heptadecanoic Acid 3-[2-[4-(6-Fluoro-1,2-benzisoxazol-3-yl)-1-piperidinyl]ethyl]-6,7,8,9-tetrahydro-2-methyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-yl Ester structure Heptadecanoic Acid 3-[2-[4-(6-Fluoro-1,2-benzisoxazol-3-yl)-1-piperidinyl]ethyl]-6,7,8,9-tetrahydro-2-methyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-yl Ester structure](https://static.chemtradehub.com/structs/140/1404053-62-8-9da4.webp)
