The first UV absorption band of l-tryptophan is not due to two simultaneous orthogonal electronic transitions differing in the dipole moment

Literature Information

Publication Date 2016-05-09
DOI 10.1039/C6CP00790B
Impact Factor 3.676
Authors


View Original

Abstract

Based on UV/Vis spectroscopic evidence obtained in this work, the first band in the absorption spectrum of L-tryptophan is largely due to a single electronic transition from the ground state to the 1Lb excited state. However, emission spectra of this compound recorded at a variable temperature in ethanol, n-butanol and diethyl ether are structureless and considerably red-shifted at room temperature; also, lowering the temperature causes the emission to become structured and to undergo such a strong blue shift that it appears to be due to the 1Lb state of the compound. Based on these findings, the formation (from the excited 1Lb state) of the excited state responsible for the structureless, markedly red-shifted emission in L-tryptophan is strongly dependent not only on the viscosity of the medium, but also on its dipolarity.

Related Literature

Palladium-catalyzed cyanation of aryl halides with in situ generated CN− from ClCF2H and NaNH2

Changjiang Yu, Xingxing Ma, Qiuling Song

2020-08-19 Research Article

DOI: 10.1039/D0QO00775G

Cavity-based applications of metallo-supramolecular coordination cages (MSCCs)

Sarita Yadav, Palanisamy Kannan, Guanyinsheng Qiu

2020-07-20 Review Article

DOI: 10.1039/D0QO00681E

Kinetic resolution of 2H-azirines via Cu(i)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides

Hua Deng, Tian-Tian Liu, Zheng-Dong Ding, Wu-Lin Yang, Xiaoyan Luo

2020-09-18 Research Article

DOI: 10.1039/D0QO00789G

An improved synthesis of the [5.6.7]-tricyclic core of cyrneine B and glaucopine C

Guo-Jie Wu, Xiu Han

2020-08-25 Research Article

DOI: 10.1039/D0QO00758G

BODIPY-amino acid conjugates – tuning the optical response with a meso-heteroatom

Marco Farinone, Joanna Cybińska, Miłosz Pawlicki

2020-06-15 Research Article

DOI: 10.1039/D0QO00481B

Nucleophile-assisted cyclization of β-propargylamino acrylic compounds catalyzed by gold(i): a rapid construction of multisubstituted tetrahydropyridines and their fused derivatives

Petr Matouš, Michal Kadaník, Marek Timoracký, Jiří Kuneš, Jana Maříková, Aleš Růžička, Milan Pour

2020-06-30 Research Article

DOI: 10.1039/D0QO00653J

Pictet–Spengler reaction based on in situ generated α-amino iminium ions through the Heyns rearrangement

Guo-bin Yang, Yong-po Zhang, Dong-dong Guo, Jin-zhong Zhao, Guang-xun Li, Zhuo Tang

2020-09-18 Research Article

DOI: 10.1039/D0QO00722F

Organic micro/nanoscale materials for photonic barcodes

Yue Hou, Zhenhua Gao, Yong Sheng Zhao, Yongli Yan

2020-08-04 Highlight

DOI: 10.1039/D0QO00613K

Modular synthesis and immunological evaluation of suspected allergenic galactooligosaccharides

Hidde Elferink, Emiel Rossing, Linqiu Cao, Dianne J. Delsing, Andre Groeneveld, Thomas J. Boltje

2019-02-26 Communication

DOI: 10.1039/C9OB00108E

Front cover

Cover

DOI: 10.1039/D0QO90065F

You might also like

Compound Q&A

Is 2-(2-chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) safe?

2-(2-Chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) is generally consi...

7765-11-92-(2-chloroacetamido...
Compound Q&A

Is 2-(Benzyloxy)-5-bromobenzoic acid (CAS: 62176-31-2) safe?

2-(Benzyloxy)-5-bromobenzoic acid can be handled safely if appropriate precautio...

62176-31-22-(Benzyloxy)-5-brom...
Compound Q&A

What is (4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride (CAS: 1159825-48-5)?

(4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride is a chemical compound ...

1159825-48-5(4-Methyl-1,2,5-oxad...
Compound Q&A

What is 2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54-7)?

2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54...

917985-54-72-(5-Hexylthiophen-2...
Compound Q&A

Are there alternatives to 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS: 102771-26-6) in synthesis?

While 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS:...

102771-26-64-(8-Methyl-9H-1,3-d...
Compound Q&A

What is the market or research trend for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine-6-carboxylate (CAS: 851376-80-2)?

The market for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine...

851376-80-2tert-butyl 3-hydroxy...
Compound Q&A

How should waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) be handled?

Waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) should ...

6844-58-23,5-Diamino-1H-pyraz...
Compound Q&A

How is (6-Fluoro-3-pyridinyl)boronic acid (CAS: 351019-18-6) typically synthesized?

(6-Fluoro-3-pyridinyl)boronic acid can be synthesized through the reaction of 6-...

351019-18-6(6-Fluoro-3-pyridiny...
Compound Q&A

What industries use Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9)?

Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9) finds applications in vario...

10065-79-9Dibenzyl carbonimido...
Compound Q&A

What is the market or research trend for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4)?

The market for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4) is g...

74228-83-4(beta,beta,2,3,4,5,6...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.