Direct isoperfluoropropylation of arenediazonium salts with hexafluoropropylene
Literature Information
Publication Date
2015-12-29
DOI
10.1039/C5QO00388A
Impact Factor
5.281
Authors
Yajun Li, Yongming Wu
View Original
Abstract
An efficient copper-promoted isoperfluoropropylation of aryl diazonium salts is described. The reaction occurs under mild conditions using commercially available hexafluoropropylene (HFP) as the starting material. In addition, a one-pot direct diazotization and isoperfluoropropylation protocol was developed. The method allows facile conversion of various arylamines into isoperfluoropropylarenes with good functional group compatibility using HFP.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
Tris(2-ethylhexyl) 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate
CAS Number:
88122-99-0
Molecular Formula:
C48H66N6O6
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