2′-Cyanoethyl thioglycosides: effective nucleophiles for synthesis of (hetero)aryl thioglycosides under the catalysis of Cu
Literature Information
Publication Date
2015-10-14
DOI
10.1039/C5QO00276A
Impact Factor
5.281
Authors
Xiaolong Yuan, Yazhen Kou, Lan Yu, Zhan-Xin Zhang, Weihua Xue
View Original
Abstract
2′-Cyanoethyl thioglycosides are designed and synthesized, which are demonstrated to function as powerful nucleophiles to a wide variety of organic iodides. The coupling reactions smoothly proceed under the catalysis of Cu to afford the corresponding (hetero)aryl thioglycosides in good to excellent yields.
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Organic Chemistry Frontiers
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