K2S2O8-mediated metal-free direct C–H functionalization of quinones using arylboronic acids

Literature Information

Publication Date 2015-10-15
DOI 10.1039/C5QO00246J
Impact Factor 5.281
Authors

Andivelu Ilangovan, Ashok Polu, Gandhesiri Satish


View Original

Abstract

Direct C–H functionalization of quinones with arylboronic acids is achieved using K2S2O8 as the sole and efficient green catalytic system. This method provides a straightforward and sustainable way to construct arylquinones via a radical pathway in moderate to good yields under metal-free conditions.

Related Literature

Co-delivery of 5-fluorocytosine and cytosine deaminase into glioma cells mediated by an intracellular environment-responsive nanovesicle

Yuanyuan Yuan, Shudong Lin, Du Cheng, Xiaoying Wang, Qing Jiang, Xintao Shuai

2014-03-25 Paper

DOI: 10.1039/C4PY00291A

A well-defined coil–comb polycationic brush with “star polymers” as side chains for gene delivery

Mingming Zhang, Qingqing Xiong, Yinsong Wang, Zhibao Zhang, Wei Shen, Lingrong Liu, Quanyao Wang

2014-04-22 Paper

DOI: 10.1039/C4PY00311J

How does a tiny terminal alkynyl end group drive fully hydrophilic homopolymers to self-assemble into multicompartment vesicles and flower-like complex particles?

Tingting Liu, Wei Tian, Yunqing Zhu, Yang Bai, Hongxia Yan, Jianzhong Du

2014-05-06 Paper

DOI: 10.1039/C4PY00501E

Synthesis and self-assembly of a novel fluorinated triphilic block copolymer

Xinxin Li, Yanhua Yang, Guojun Li

2014-04-22 Paper

DOI: 10.1039/C4PY00308J

Synthesis and characterization of isosorbide-based polyphosphonates as biobased flame-retardants

Timothy C. Mauldin, Jeffrey W. Gilman, John R. Shields, Dylan J. Boday

2014-06-02 Paper

DOI: 10.1039/C4PY00591K

Front cover

Cover

DOI: 10.1039/C4PY90050B

Back cover

Cover

DOI: 10.1039/C4PY90044H

Stability of star-shaped RAFT polystyrenes under mechanical and thermal stress

Mahdi Abbasi, Kamran Riazi, Nico Dingenouts, Manfred Wilhelm

2014-05-08 Paper

DOI: 10.1039/C4PY00484A

You might also like

Compound Q&A

What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?

Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...

10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A

How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?

Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...

34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A

How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?

Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...

858-46-82,4,6-Tris(pentafluo...
Compound Q&A

What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?

When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...

56787-36-1Chloroac-nle-oh
Compound Q&A

What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?

Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...

752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A

Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?

Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...

55095-15-3alpha-(2-Bromophenyl...
Compound Q&A

How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?

Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...

139585-48-12-Chloro-5-methoxypy...
Compound Q&A

What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?

1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...

5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A

Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?

There are alternative reagents and compounds that can be used in the synthesis o...

903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A

What is Tungsten(IV) oxide (CAS: 12036-22-5)?

Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...

12036-22-5Tungsten(IV) oxide

Source Journal

Organic Chemistry Frontiers

Organic Chemistry Frontiers
CiteScore: 7.8
Self-citation Rate: 8.7%
Articles per Year: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.