Alkylation/1,2-aryl migration of α-aryl allylic alcohols with α-carbonyl alkyl bromides using visible-light photoredox catalysis
Literature Information
Publication Date
2015-09-01
DOI
10.1039/C5QO00220F
Impact Factor
5.281
Authors
Yang Li, Bang Liu, Xuan-Hui Ouyang, Ren-Jie Song
View Original
Abstract
A novel visible-light-induced alkene difunctionalization strategy is described for the synthesis of 1,5-dicarbonyl compounds from two reaction partners, α-aryl allylic alcohols and α-carbonyl alkyl bromides. This method is successful by sequential alkylation of an alkene C–C double bond and intramolecular 1,2-aryl migration, and shows a broad substrate scope, excellent functional group tolerance and good selectivity.
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Organic Chemistry Frontiers
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