4-(4-Chloro-2-methoxyphenyl)-3-fluorobenzoic acid
CAS Number:
1261970-23-3
Molecular Formula:
C14H10ClFO3
Polymer/zinc hybrid-flow battery using block copolymer micelles featuring a TEMPO corona as catholyte
Literature Information
Publication Date
2016-01-19
DOI
10.1039/C5PY02036K
Impact Factor
5.582
Authors
Mark Billing, Guillaume Hauffman, Jean-François Gohy, Stephanie Hoeppener
View Original
Abstract
A well-defined block copolymer was applied in a semi-organic polymer hybrid-flow battery (pHFB). A 2,2,6,6-tetramethylpiperidinyl-N-oxyl (TEMPO) containing polymer was utilised as cathode active material. Micellar structures of the active material were achieved by utilising a diblock copolymer composed of a polar poly(TEMPO methacrylate) (PTMA) and an unpolar poly(styrene) (PS) block, which enables the formation of core-corona micelles in organic carbonates. The synthesised PTMA-b-PS was electrochemically investigated and subsequently utilised as catholyte in polymer/Zn pHFBs. The constructed flow batteries feature an excellent cycling stability of 1000 consecutive charge/discharge cycles with 95% retention of initial discharge capacity and a stable voltage range of 2 V. Further, the charging process leads to slight changes in the micellar structure combined with an increased solubility.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![2-(5-Bromo-1H-pyrrolo[2,3-B]pyridin-3-YL)acetic acid structure](https://static.chemtradehub.com/structs/106/1060795-03-0-0589.webp "2-(5-Bromo-1H-pyrrolo[2,3-B]pyridin-3-YL)acetic acid structure")
2-(5-Bromo-1H-pyrrolo[2,3-B]pyridin-3-YL)acetic acid
CAS Number:
1060795-03-0
Molecular Formula:
C9H7BrN2O2
![4-Fluoro-2-(4-{[(3S,4R)-4-(2-hydroxy-2-propanyl)-3-pyrrolidinyl]amino}-6,7-dimethoxy-2-quinazolinyl)phenol hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/143/1431697-96-9-619c.webp "4-Fluoro-2-(4-{[(3S,4R)-4-(2-hydroxy-2-propanyl)-3-pyrrolidinyl]amino}-6,7-dimethoxy-2-quinazolinyl)phenol hydrochloride (1:1) structure")
4-Fluoro-2-(4-{[(3S,4R)-4-(2-hydroxy-2-propanyl)-3-pyrrolidinyl]amino}-6,7-dimethoxy-2-quinazolinyl)phenol hydrochloride (1:1)
CAS Number:
1431697-96-9
Molecular Formula:
C23H28ClFN4O4
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