![(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure](https://static.chemtradehub.com/structs/126/1269757-29-0-c552.webp "(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure")
(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid
CAS Number:
1269757-29-0
Molecular Formula:
C15H19NO4
Synthesis of a new poly([R]-3-hydroxybutyrate) RAFT agent
Literature Information
Publication Date
2016-01-04
DOI
10.1039/C5PY01812A
Impact Factor
5.582
Authors
Lu Jiang, Sing Shy Liow
View Original
Abstract
Poly[(R)-3-hydroxybutyrate] (PHB) has attracted more and more attention in biomedical applications in recent years, due to its excellent properties of sustainability, biodegradability and biocompatibility. In this work, purified natural PHB was modified by 1-hexanol through transesterification reaction to form mono-hydroxylated PHB. The kinetic process of transesterification was carefully investigated. The mono-hydroxylated PHB was reacted with the thiocarbonylthio compound to generate a biodegradable macro mono-hydroxylated PHB chain transfer agent (CTA), which could react with other monomers to produce block copolymers. The monomer, 2-dimethylaminoethyl methacrylate (DMAEMA) was chosen to demonstrate the copolymerization process and the block copolymer PHB-b-PDMAEMA was obtained.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride
CAS Number:
1329799-67-8
Molecular Formula:
C7H2ClD6NO2
cis-3-Amino-1-(trifluoromethyl)cyclobutanol hydrochloride (1:1)
CAS Number:
1408075-16-0
Molecular Formula:
C5H9ClF3NO
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