Chloride-promoted Pd-catalyzed direct C–H arylation for highly efficient phosphine-free synthesis of π-conjugated polymers

Literature Information

Publication Date 2015-06-19
DOI 10.1039/C5PY00871A
Impact Factor 5.582
Authors

Shotaro Hayashi, Toshio Koizumi


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Abstract

We have successfully demonstrated a chloride-promoted Pd-catalyzed phosphine-free direct C–H arylation for highly efficient synthesis of high molecular weight π-conjugated polymers. Among halide ions, chloride ions played a crucial role in highly efficient C–H activation.

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Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
Self-citation Rate: 7.3%
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Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

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