α-(Aminomethyl)acrylate: polymerization and spontaneous post-polymerization modification of β-amino acid ester for a pH/temperature-responsive material
Literature Information
Publication Date
2015-06-16
DOI
10.1039/C5PY00723B
Impact Factor
5.582
Authors
Yasuhiro Kohsaka, Yusuke Matsumoto, Tatsuki Kitayama
View Original
Abstract
Ethyl α-(aminomethyl)acrylate, a β-amino acid ester carrying a conjugated vinylidene group at the α-position, was radically polymerized. The polymerization was found to involve subsequent ester–amide exchange reaction between the amino pendants of the polymer and an ester group of the monomer, affording acrylamide-bearing units in 11–15% contents. The obtained polymer exhibited pH/temperature responsiveness in aqueous media.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide
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Molecular Formula:
C49H37F3NO5PS
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4-(4-Chloro-2-methoxyphenyl)-3-fluorobenzoic acid
CAS Number:
1261970-23-3
Molecular Formula:
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