Combined friction force microscopy and quantum chemical investigation of the tribotronic response at the propylammonium nitrate–graphite interface

Literature Information

Publication Date 2015-05-26
DOI 10.1039/C5CP01952D
Impact Factor 3.676
Authors

H. Li, R. Atkin, A. J. Page


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Abstract

The energetic origins of the variation in friction with potential at the propylammonium nitrate–graphite interface are revealed using friction force microscopy (FFM) in combination with quantum chemical simulations. For boundary layer lubrication, as the FFM tip slides energy is dissipated via (1) boundary layer ions and (2) expulsion of near-surface ion layers from the space between the surface and advancing tip. Simulations reveal how changing the surface potential changes the ion composition of the boundary and near surface layer, which controls energy dissipation through both pathways, and thus the friction.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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