(1R,2R)-2-Methylcyclohexanamine hydrochloride (1:1)
CAS Number:
39558-31-1
Molecular Formula:
C7H16ClN
Fe(0) powder-catalyzed one-pot reaction: concurrent living radical polymerization and click chemistry for topological polymers
Literature Information
Publication Date
2015-05-26
DOI
10.1039/C5PY00654F
Impact Factor
5.582
Authors
Hui Zhu, Zhenbiao Zhang, Nianchen Zhou, Xiulin Zhu
View Original
Abstract
Fe(0) powder-catalyzed one-pot reaction was successfully employed to design linear and star polymers in a well-controlled manner by combining ambient temperature living radical polymerization and click chemistry. The polymerization behavior possessed the characteristics of “living”/controlled radical polymerization: the first-order kinetic plots, narrow molecular weight distribution (PDI < 1.4), the linear relationship between molecular weights and the monomer conversions and the successful chain-extension with a NIPAAM monomer. Furthermore, the NMR and MALDI-TOF-MS data indicated that the Fe(0)-catalyzed one-pot strategy is different from our reported Cu(0)-catalyzed one-pot strategies to make the targeted polymers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
4-(3-((4-Chloro-6-methoxyquinolin-7-yl)oxy)propyl)morpholine
CAS Number:
205448-32-4
Molecular Formula:
C17H21ClN2O3
4-(4-Methoxyphenyl)-5-methyl-1,3-thiazol-2-amine
CAS Number:
105512-88-7
Molecular Formula:
C11H12N2OS
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