Stereoregular poly(methyl methacrylate) with double-clickable ω-end: synthesis and click reaction
Literature Information
Publication Date
2015-04-14
DOI
10.1039/C5PY00357A
Impact Factor
5.582
Authors
Yasuhiro Kohsaka, Kazuki Yamamoto, Tatsuki Kitayama
View Original
Abstract
Isotactic and syndiotactic poly(methyl methacrylate)s with orthogonally double-clickable terminal ends, that is, α,β-unsaturated esters for Michael addition-type thiol–ene reactions and azide or alkynyl groups for azide–alkyne click reactions, were prepared via a terminating reaction of stereospecific anionic polymerization with propargyl and 2-chloroethyl α-(chloromethyl)acrylates. The subsequent polymer modification via a double click reaction proceeded quantitatively in a one-pot system under ambient conditions. The facile and almost quantitative double-end-functionalization would open a new material design based on stereoregular PMMAs with controlled molecular weights.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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CAS Number:
1431697-96-9
Molecular Formula:
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4-(3-((4-Chloro-6-methoxyquinolin-7-yl)oxy)propyl)morpholine
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Molecular Formula:
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