Functional polyesters derived from alternating copolymerization of norbornene anhydride and epoxides
Literature Information
Publication Date
2015-04-07
DOI
10.1039/C5PY00119F
Impact Factor
5.582
Authors
Ryan Baumgartner, Ziyuan Song, Yanfeng Zhang
View Original
Abstract
Herein, we report the synthesis of polyesters via the alternating copolymerization of epoxides and cis-5-norbornene-endo-2,3-dicarboxylic anhydride (NB). The polymers are demonstrated to be of perfectly alternating structure with monomodal peak distributions and low polydispersity indexes. We demonstrate that these polyesters can be functionalized using thiol–ene and tetrazine click chemistry to form polymers with alternating functionality. Furthermore, we show that these polymers can be made thermally responsive, and can even be crosslinked when mixed with Grubbs’ catalyst.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Recommended Compounds
![2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/253/25332-39-2-496e.webp "2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure")
2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1)
CAS Number:
25332-39-2
Molecular Formula:
C19H23Cl2N5O
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