Nonpolar nitrous oxide dimer: fundamentals of the mixed 14N2O–15N2O dimer and new combination bands of (14N2O)2 and (15N2O)2 involving the Bu intermolecular bend

Literature Information

Publication Date 2009-07-01
DOI 10.1039/B905373E
Impact Factor 3.676
Authors

M. Dehghany, Mahin Afshari, Z. Abusara, N. Moazzen-Ahmadi


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Abstract

Spectra of the nonpolar nitrous oxide dimer in the region of the N2O ν1 fundamental band are observed in a pulsed supersonic slit jet expansion probed with a tunable diode laser. Four bands are analysed: two fundamentals of the mixed 14N2O–15N2O dimer and combination bands involving the intermolecular disrotation of the monomers (Bu intermolecular bend) for both (14N2O)2 and (15N2O)2. Because the determination of this intermolecular frequency relies on the experimentally unknown frequency of the (forbidden) symmetric fundamental, we used previously published ab initio results and their proximity to our experimental values to assign the upper state of the combination bands. The resulting intermolecular disrotation frequencies are 42.3(1.0) and 41.6(1.0) cm−1 for the (14N2O)2 and (15N2O)2, respectively. This represents the first observation of the mixed 14N2O–15N2O dimer, and the direct determination of a second intermolecular frequency for the nonpolar (N2O)2.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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