Concentration-dependent apparent partition coefficients of ionic liquids possessing ethyl- and bi-sulphate anions

Literature Information

Publication Date 2015-11-25
DOI 10.1039/C5CP06611E
Impact Factor 3.676
Authors

Preeti Jain, Anil Kumar


View Original

Abstract

This study deals with the concentration dependent apparent partition coefficients log P of the ethyl and bisulfate-based ionic liquids. It is observed that the bisulfate-based ionic liquids show different behaviour with respect to concentration as compared to ethyl sulphate-based ionic liquids. It is significant and useful analysis for the further implementation of alkyl sulfate based ionic liquids as solvents in extraction processes. The log P values of the ethyl sulphate-based ionic liquids were noted to vary linearly with the concentration of the ionic liquid, whereas a flip-flop trend with the concentration for the log P values of the bisulphate-based ionic liquids was observed due to the difference in hydrogen bond accepting basicity and possibility of aggregate formation of these anions. The π–π interactions between the imidazolium and pyridinium rings were seen to affect the log P values. The alkyl chain length of anions was also observed to influence the log P values. The hydrophobicity of ionic liquid changes with the alkyl chain in the anion in the order; [HSO4]− < [EtSO4]− < [BuSO4]−.

Related Literature

Back cover

2024-01-22 Cover

DOI: 10.1039/D4CS90007C

Heterometallic cages: synthesis and applications

2023-12-01 Tutorial Review

DOI: 10.1039/D3CS00690E

Template-assisted synthesis of isomeric copper(i) clusters with tunable structures showing photophysical and electrochemical properties

Jun-Jie Fang, Zheng Liu, Yang-Lin Shen, Yun-Peng Xie, Xing Lu

2023-10-13 Edge Article

DOI: 10.1039/D3SC04682F

Nickel-catalysed asymmetric hydromonofluoromethylation of 1,3-enynes for enantioselective construction of monofluoromethyl-tethered chiral allenes

Ying Zhang, Jimin Yang, Yu-Long Ruan, Ling Liao, Chuang Ma

2023-10-23 Edge Article

DOI: 10.1039/D3SC04474B

Photocatalysis with atomically thin sheets

Yingying Fan, Jinguang Hu, Hyeon Suk Shin, Damien Voiry, Qingye Lu, Jimmy C. Yu

2023-10-25 Tutorial Review

DOI: 10.1039/D2CS00205A

Pursuing excitonic energy transfer with programmable DNA-based optical breadboards

Divita Mathur, Sebastián A. Díaz, Ryan D. Pensack, Bernard Yurke, Austin Biaggne, Joseph S. Melinger, William B. Knowlton, Igor L. Medintz

2023-10-24 Review Article

DOI: 10.1039/D0CS00936A

Contents list

2023-11-13 Front/Back Matter

DOI: 10.1039/D3CS90090H

Back cover

2023-11-27 Cover

DOI: 10.1039/D3CS90095A

Nuclear localization signal-tagged systems: relevant nuclear import principles in the context of current therapeutic design

Ritabrita Goswami, Aarohi Gupta, Olga Bednova, Gaël Coulombe, Dipika Patel, Vincent M. Rotello

2023-11-30 Review Article

DOI: 10.1039/D1CS00269D

Reactivity of metal–oxo clusters towards biomolecules: from discrete polyoxometalates to metal–organic frameworks

David E. Salazar Marcano, Nada D. Savić, Kilian Declerck, Shorok A. M. Abdelhameed, Tatjana N. Parac-Vogt

2023-11-28 Review Article

DOI: 10.1039/D3CS00195D

You might also like

Compound Q&A

What are the main uses of (3alpha,5alpha)-3-Hydroxypregnane-11,20-dione (CAS: 23930-19-0)?

(3alpha,5alpha)-3-Hydroxypregnane-11,20-dione is primarily used in the pharmaceu...

23930-19-0(3alpha,5alpha)-3-Hy...
Compound Q&A

What is the market or research trend for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4)?

The market for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4) is ...

546141-56-44-Amino-6-chloro-2-p...
Compound Q&A

Are there alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in synthesis?

Alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in ...

24472-88-6(2-Benzoylethyl)trim...
Compound Q&A

Is N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) safe?

N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) is generally safe...

393-12-4N-[4-Nitro-3-(triflu...
Compound Q&A

Are there alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-14-5) in synthesis?

There are alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-...

4605-14-5N,N'-Bis(3-aminoprop...
Compound Q&A

What precautions should be taken when handling Aluminium trihexadecanoate (CAS: 555-35-1)?

When handling Aluminium trihexadecanoate, it is important to use appropriate per...

555-35-1Aluminium trihexadec...
Compound Q&A

What is (1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid (CAS: 52188-11-1)?

(1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid is a chemical compound ...

52188-11-1(1,1-Dioxido-3-oxo-1...
Compound Q&A

Are there alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) in synthesis?

Several alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) can be used in...

3123-97-55,5-dimethyloxolan-2...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.