Experimental evidence for the influence of charge on the adsorption capacity of carbon dioxide on charged fullerenes
Literature Information
Stefan Ralser, Alexander Kaiser, Michael Probst, Johannes Postler, Michael Renzler, Diethard K. Bohme, Paul Scheier
We show, both experimentally and theoretically, that the adsorption of CO2 is sensitive to charge on a capturing model carbonaceous surface. In the experiment we doped superfluid helium droplets with C60 and CO2 and exposed them to ionising free electrons. Both positively and negatively charged C60(CO2)n+/− cluster ion distributions are observed using a high-resolution mass spectrometer and they show remarkable and reproducible anomalies in intensities that are strongly dependent on the charge. The highest adsorption capacity is seen with C60+. Complementary density functional theory calculations and molecular dynamics simulations provided insight into the nature of the interaction of charged C60 with CO2 as well as trends in the packing of C60+ and C60−. The quadrupole moment of CO2 itself was found to be decisive in determining the charge dependence of the observed adsorption features. Our findings are expected to be applied for the adsorption of CO2 on charged surfaces in general.
Related Literature
Interfacial phenomena in (de)hydrogenation reactions
Jinlong Gong, Zhihong Nie, Xinbin Ma
DOI: 10.1039/C3CP90089D
A rapid identification of hit molecules for target proteins via physico-chemical descriptors
Goutam Mukherjee
DOI: 10.1039/C3CP44697B
Synthesis and characterization of the crystal structure and magnetic properties of the hydroxyfluoride MnF2−x(OH)x (x ∼ 0.8)
Hamdi Ben Yahia, Masahiro Shikano, Hironori Kobayashi, Maxim Avdeev, Samuel Liu, Chris D. Ling
DOI: 10.1039/C3CP50740H
Membrane disordering is not sufficient for membrane permeabilization by islet amyloid polypeptide: studies of IAPP(20–29) fragments
Jeffrey R. Brender, Deborah L. Heyl, Shyamprasad Samisetti, Samuel A. Kotler, Joshua M. Osborne, Ranadheer R. Pesaru, Ayyalusamy Ramamoorthy
DOI: 10.1039/C3CP44696D
Analytical model and multiscale simulations of Aβ peptide aggregation in lipid membranes: towards a unifying description of conformational transitions, oligomerization and membrane damage
Martina Pannuzzo, Danilo Milardi, Antonio Raudino, Mikko Karttunen, Carmelo La Rosa
DOI: 10.1039/C3CP44539A
Bistable memory devices with lower threshold voltage by extending the molecular alkyl-chain length
Wusheng Ren, Yongxiang Zhu, Jianfeng Ge, Xufeng Xu, Ru Sun, Najun Li, Hua Li, Qingfeng Xu, Junwei Zheng, Jianmei Lu
DOI: 10.1039/C3CP51290H
Remarks on time-dependent [current]-density functional theory for open quantum systems
DOI: 10.1039/C3CP51127H
Effects of membrane interaction and aggregation of amyloid β-peptide on lipid mobility and membrane domain structure
Kenji Sasahara, Kyoko Shinya
DOI: 10.1039/C3CP44517H
You might also like
What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?
1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...
How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?
Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...
What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?
Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...
Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?
Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...
How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?
Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...
What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?
6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...
What is the market or research trend for 3-(3,4-dimethoxyphenyl)-2,5-dimethyl-N-(2-morpholin-4-ylethyl)pyrazolo[1,5-a]pyrimidin-7-amine (CAS: 900874-91-1)?
Research trends for this compound indicate a focus on its potential applications...
How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?
9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...
How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?
1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...
How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?
Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![Sodium (2Z)-7-{[(2R)-2-amino-2-carboxyethyl]sulfanyl}-2-({[(1S)-2,2-dimethylcyclopropyl]carbonyl}amino)-2-heptenoate structure Sodium (2Z)-7-{[(2R)-2-amino-2-carboxyethyl]sulfanyl}-2-({[(1S)-2,2-dimethylcyclopropyl]carbonyl}amino)-2-heptenoate structure](https://static.chemtradehub.com/structs/811/81129-83-1-441c.webp)
