A theoretical study of sum-frequency generation for chiral solutions near electronic resonance

Literature Information

Publication Date 2015-07-06
DOI 10.1039/C5CP02136G
Impact Factor 3.676
Authors

Ren-hui Zheng, Wen-mei Wei, Qiang Shi


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Abstract

We present a method of calculating sum-frequency generation (SFG) for chiral solutions near electronic resonance including the vibronic contributions, which give reasonable SFG intensities and show the Franck–Condon progressions for SFG. When studying R-1,1′-bi-2-naphthol (R-BN), we found that the calculated spectrum is in good agreement with the experimental one (Phys. Rev. Lett., 2001, 87, 113001). Then we apply this method to investigate SFG for chiral arabinose solutions. Theoretical results show that it may be difficult to observe the corresponding SFG even when the sum-frequency is exactly in resonance with the low-lying excited electronic states. Furthermore, we discuss the reason why SFG of chiral arabinose solutions is small.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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