Ring-opening polymerization of a 2,3-disubstituted oxirane leading to a polyether having a carbonyl–aromatic π-stacked structure
Literature Information
Publication Date
2015-01-16
DOI
10.1039/C4PY01711K
Impact Factor
5.582
Authors
Yasuhito Koyama, Hiroyasu Sato, Li Geng, Vakhtang Barbakadze, Bezhan Chankvetadze, Tamaki Nakano
View Original
Abstract
2-Methoxycarbonyl-3-(3,4-dimethoxyphenyl)oxirane was synthesized and polymerized using a cationic initiator to afford a polymer having a rather stiff, stretched conformation. The side-chain methoxycarbonyl group and 3,4-dimethoxyphenyl group of neighboring monomeric units may form a hetero π-stacked structure between side-chain carbonyl and aromatic groups which leads to intramolecular charge transfer (ICT) interactions. 2-Ethoxycarbonyl-3-phenyloxirane failed in polymerization, leading only to small molecules including cyclic compounds.
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Source Journal
Polymer Chemistry
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