Rational design of a fluorescent poly(N-aryleneindole ether sulfone) switch by cation–π interactions
Literature Information
Guanjun Chang, Li Yang, Shenye Liu, Runxiong Lin, Jingsong You
Semirigid poly(N-aryleneindole ether sulfone) (PESIN) as a fluorescence emission on–off switch has been successfully achieved via the cation–π interactions. The adjustment of the protonation/deprotonation status of pyridine that regulates the formation of cation–π interactions is definitely the determinant.
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![N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure](https://static.chemtradehub.com/structs/122/1227374-64-2-cdb5.webp)


