Synthesis and properties of a well-defined copolymer of chlorotrifluoroethylene and N-vinylpyrrolidone by xanthate-mediated radical copolymerization under 60Co γ-ray irradiation

Literature Information

Publication Date 2014-07-24
DOI 10.1039/C4PY00902A
Impact Factor 5.582
Authors

Pucheng Wang, Jingwen Dai, Lei Liu, Qibao Dong, Hu Wang, Ruke Bai


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Abstract

Living/controlled radical copolymerization of chlorotrifluoroethylene and N-vinylpyrrolidone has been successfully achieved at room temperature under 60Co γ-ray irradiation in the presence of ethyl 2-(ethoxycarbonothioylthio)acetate. The living/controlled character of the polymerization was confirmed by GPC and NMR analyses, as well as the chain extension polymerization. The physical properties of the obtained polymers were investigated and the experimental results indicate that the fluorinated copolymer showed excellent film-forming characteristics and high mechanical properties. Moreover, the fluorinated amphiphilic block copolymers prepared by chain extension polymerization show good biocompatibility.

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Polymer Chemistry

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