Solvent-tuned dual emission: a structural and electronic interplay highlighting a novel planar ICT (OPICT)
Literature Information
S. Chevreux, R. Paulino Neto, C. Allain, K. Nakatani, P. Jacques, I. Ciofini, G. Lemercier
Displaying a dual emission, a Phen-PENMe2 compound can be foreseen as a new model for fundamental studies. It is based on an excited state cumulene-type structure, involving orthogonal π orbital (OPICT). In contrast to the “Twisted Intramolecular Charge Transfer” (TICT) emission, the OPICT emissive state is planar. This new compound is also a potential candidate for local ratiometric probes of medium polarity (mixture of solvents and biological systems) and white emission.
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