Direct evidence for a substantive reaction between the Criegee intermediate, CH2OO, and the water vapour dimer
Literature Information
Tom R. Lewis
The C1 Criegee intermediate, CH2OO, reaction with water vapour has been studied. The removal rate constant shows a quadratic dependence on [H2O], implying reaction with the water dimer, (H2O)2. The rate constant, kCH2OO+(H2O)2 = (4.0 ± 1.2) × 10−12 cm3 molecule−1 s−1, is such that this is the major atmospheric sink for CH2OO.
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