Direct evidence for a substantive reaction between the Criegee intermediate, CH2OO, and the water vapour dimer

Literature Information

Publication Date 2015-01-19
DOI 10.1039/C4CP04750H
Impact Factor 3.676
Authors

Tom R. Lewis


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Abstract

The C1 Criegee intermediate, CH2OO, reaction with water vapour has been studied. The removal rate constant shows a quadratic dependence on [H2O], implying reaction with the water dimer, (H2O)2. The rate constant, kCH2OO+(H2O)2 = (4.0 ± 1.2) × 10−12 cm3 molecule−1 s−1, is such that this is the major atmospheric sink for CH2OO.

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Back matter

Front/Back Matter

DOI: 10.1039/B919883K

Inside front cover

Front/Back Matter

DOI: 10.1039/B920361N

Front cover

Cover

DOI: 10.1039/C0CP90075C

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