On the nature of hydrogen bonds to platinum(ii) – which interaction can predict their strength?
Literature Information
Rocío Sánchez-de-Armas, Mårten S. G. Ahlquist
The interaction between hydrogen bond donors and platinum has been analysed. Our results point to an interaction that can be entirely predicted from the dz2 orbital energy of the platinum centre indicating strong charge transfer, with significant dispersion contribution to the bonding, very different from classical hydrogen bonds.
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